JNIOSH

Abstract of Special Research Report (RR-23)

National Institute of Occupational Safety and Health, Japan

Evaluation of Dust Explosivility --Lower Limits and Explosion Pressures--

RR-23-1
Michio NAITO and Toei MATSUDA

: The evaluation of dust explosibility is still of practical importance because it is quite difficult to predict the characteristics of the dust explosion hazards only from the properties of fine combustible materials. Also present knowledge of the dust combustion do not necessarily show whether an explosion, arises with the dust.
    An attempt has been made on evaluating the explosibility in comparison with lower concentration limits and explosion pressures. The measurements of the lower limits and explosion pressures were conducted with the widely used vertical tube apparatus for some chemical and plastic powders. They are shown in Table 1., where the lower concentrations are given in the range between nil and 100 per cent of explosion frequency. Here, the explosion frequency represents the ratio of combustions in at least ten trials for the same weight of dust samples.
    The method itself involves many factors effecting the results and one of the governing factors would be the non-uniform dispersibility of dust in the combustion tube. As shown in Fig.2, the flame is extremely turbulent and seems not to occupy the whole volume of the apparatus. This leads the measured minimum explosible concentration would not have high accuracy or absolute limits, but the comparative values are expected to give the evaluation of explosibility.
    Effect of particle sizes on the lower limits is shown in Fig.3 for polypropylene and telephthalic acid, that is, above a certain coarseness the flame propagation become very difficult.
    Explosion pressures were measured in a closed tube and an example of time-pressure records is illustrated in Fig.5. Effect of dispersing air pressures on explosion pressures is shown in Fig.6. When a weighed amount of dust is dispersed in the closed tube by the release of high pressure air, the dust particles are in the strong disturbance and then, it would be reasonable to consider the explosion of the dust-air mixture under pressure for the closed apparatus. It was concluded desirable to use the explosion pressure ratio, that is the explosion pressure against dispersion air pressure. A correction is made also for the dust concentration due to the dispersion air. At higher concentrations, it is, however, quite difficult to attain the full dispersion of the dust. Effect of particle sizes on explosion pressures is given in Fig.9 for polypropylene dust. It shows that the maximum explosion pressure becomes almost independent of fineness at last above a certain fineness.
    Gas analysis after the combustion in the closed tube was made for oxygen, carbon mono and dioxide. The results are shown in Fig.11, against dust concentrations. Polypropylene and polyethylene powders contain relatively high proportion of toxic carbon mono-oxide in the burned mixtures.
    The method and apparatus are still insufficient and have some limitations, but it may be concluded that the evaluation of dust explosibility is made on explosion parameters.

Critical Oxygen Concentration for the Combustion of Polyethylene and Polypropylene Dusts

RR-23-2
Michio NAITO and Toei MATSUDA

: Critical oxygen concentration have been measured for the combustion of PE (high density polyethylene) and PP (polypropylene) dusts with a vertical tube apparatus to make sure whether the oxygen concentrations determined with a relatively small apparatus would be applicable to large scale powder handling systems. For the practical application, nitrogen gas had been chosen as inert.
    The apparatus shown in Fig.1 consisted of a vertical explosion tube of clear perspex, 15 cm in diameter and 1.9 m long. Dust clouds of various concentrations Could be produced by varying the speed of screw conveyor. The oxygen concentration of the atmosphere was controlled by passing the flow of ratios of O2 / ( O2 + N2 ) through a gas mixer and checked in top of the tube with a magnetic oxygen analyser after efficient purging within the tube. The experiment was carried out at a closed end ignition and with ignition sources of hot nichrom wire (AC 20V, 14A) and a piece of gun cotton (0.5g) initiated from spark.
    The results of the experiments with ignition of hot wires are summarized in Fig.2 in which the effects of particle size on flammability of PP dusts are shown. It can be seen that the critical oxygen concentration varies greatly with the particle sizes and ignition sources. The amounts of gun cotton were increased up to 10 g, but the results remained unchanged. In the PP dust passing a 200 standard sieve, the critical oxygen concentration is 12.2 per cent for the use of hot wire ignition and 11.4 per cent for the ignition by gun cotton (Fig.3). Similar results of experiments with PE dust are shown in Fig.4, from which it was also shown that the critical value is 13.0 per cent for the hot wire ignition and ll. 4 per cent for the gun cotton ignition. The flammability boundaries of PE and PP dusts in the atmosphere are summarized in Fig.4.
    Although the sample dusts had passed through a sieve of the same mesh number No.200 (openings 74 microns), it was confirmed with a microscope that particle sizes and its distribution differed for both powders : the most frequent mean particle diameter was 28 microns for PP and 70 microns for PE. Then, the difference of particle size distribution rather than chemical structure would have resulted in the oxygen values of 12.2 per cent for PP and 13.0 per cent for PE when obtained by hot wire ignition. With gun cotton ignition, however, the identical oxygen values were obtained for both samples in spite of the difference of particle sizes. This was taken as evidence that the source of ignition has a large power density.
    The flammability boundaries obtained with hot wires could be estimated to belong to the ignition limits which are affected by the size of the ignition source.

Interruption of Explosions by Flame Arresters (2nd Report) --Quenching of Gaseous Detonations by Wire Gauzes--

RR-23-3
Toshihiro HAYASHI

: Detonation, a shock wave supported energetically by chemical reactions in flames, is a most dangerous form of flame propagation through explosive media. Interruption of detonation is, therefore, an important technique to prevent serious disasters in such processes as flammable gas conveying pipelines. Gases are seldom premised with air, but atmospheric air often invades into gas lines through various leak processes. It would be better to consider that an ignition of explosive mixture leads finally to a detonation in a long line, and to insert effective detonation arrester in such pipelines to minimize the resulting damages.
    This report describes about the decaying of a detonation wave by inserting a perforated plate in a detonating tube, and the direct interruption of detonation by layered wire gauzes supported with a perforated plate. Experiments are carried out in a 1-inch tube (Fig.1), and the arrester housing (Fig.2) contains wire gauzes and/or a perforated plate under test. Combustible mixture used is that of stoichiometric hydrogen-air with initial pressures below 1 kg/cm2 (G). After the ignition of the mixture at the far end of the tube, flame is so accelerated by a spiral insertion as to develop to an incidental detonation wave onto the arrester housing.
    To determine the effect of perforated plate on detonation decaying, plates in Fig.3 are tested. Each plate is specified by a diameter of one hole D 0 and a number of equi-diameter holes N. An average flame speed V a.b between two points, one before and the other after the tested plate, is measured by the ion-gap method. If detonation is decayed through the plate, V a.b differs from the detonation velocity depending on the degree of decaying. Main results are as follows ;
  (1) For each plate V a.b is not effected by the initial gas pressure. For plates with one hole, D 0 can be related with V a.b as shown in Fig.7. From this relation, a corresponding single hole diameter (D E) of each plate with N ≥ 2 can be given ; D E is defined as a hole diameter of the plate with N = 1 which gives the same V a.b as that measured for the plate under consideration.
  (2) The relation between D E and D ( = √N D 0) shows that the degree of decaying is determined by a total open area of holes for plates with rather larger D , and that plates with suber 5 decay detonations more effectively than estimated from N and D 0 of those plates. Thus, D E can be used to denote the relative degree of detonation decaying by any perforated plate (Fig.8).
  (3) D E is also related to the flow resistance of each plate, but because of the dependency of the flow resistance on N and D 0, the relation between D E and the flow resistance is found to be nearly same as that between D E and D .
  (4) As a whole, a perforated plate with a large number of holes of suber diameter may practically be useful from the standpoints of the effect on detonation decaying and the flow resistance togas flows.
    Flame quenching abilities of wire gauzes are studied for commercial filter gauzes (Table 1). They are not so strong as to stand against repeated shock pressures by themselves that they must be supported by a perforated plate. As flames more easily pass through gauzes for higher initial gas pressures, the maximum initial pressure which gives three successive quenchings is denied as the Limiting Safe Pressure (L.S.P.) to compare a relative quenching ability of gauzes. Thus, a high L.S.P. means a high quenching ability of gauzes.
    Main results on detonation quenchings are as follows ;
  (1) The open area of holes of a supporting perforated plate effects largely on the flame quenching : decreasing D always increases the L.S.P. (Fig.9).
  (2) Effects of the thickness of layered gauzes on the L.S.P. are more distinct for larger holes in supporting plates (Fig.10). The rate of increasing the L.S.P. gradually decreases as the thickness of the gauze layer increases. Five packs of gauze supported by an adequate perforated plate will quench all flames of hydrogen-air detonations under studied conditions.
  (3) Flow resistances of packed gauzes with a perforated plate can be related with the L.S.P. (Fig.13). For more than three packs of gauze, the flow resistance gives a little influence on quenching abilities.
    From these results the mechanism of detonation quenching may be roughly assumed ; the first process is a decaying of a detonation wave at the entrance into the surface of wire gauzes, and the second is a process of flame quenching or heat losses to gauze metals. Thus, detonation arresters are said to be flame arresters with mechanical structures for detonation decaying.

Fatigue of Vitrified Grinding Wheel

RR-23-4
Soichi KUMEKAWA

: In general, the fluctuating stress varied according to change of rotating speed and to another operating condition applies on grinding wheels.
    For example followings are supposed.
  (1) In usual operating
    a) fluctuating stress when rotating speed varies from stationary state to rating speed (in trial run)
    b) fluctuating stress by change of grinding load in addition to above (in grinding)
  (2) In the inspection for strength guarantee of grinding wheels, fluctuating stress when the rotating speed varies form stationary state to the testing speed, etc.
    In addition, it is supposed that some fluctuating stress by mechanical vibration applies on grinding wheels in all operating state.
    Therefore the observation of the strength behaviours under the fluctuating stress state is very important in order to arrange the safety use of grinding wheels.
    Then we tried the repeating tensile test of vitrified test pieces which were quarried from vitrified grinding wheels and other few test about them.
    Grinding wheels used in this experiment are grain A, grain-size 60 and grade I.L.O.R.
    The results are as the following,
  (1) The results of centrifuge test are shown in Fig.4.
  (2) The results of statical tensile test are shown in Fig.5,

  where         σt = P t / A [ kg/cm2 ]
      P t : breaking load in statical tensile test [kg]
      A : effective sectional area [ cm2 ]
  (3) In the repeating tensile test we tried one-side repeating tensile test with the stress amplitudes which were about onehalf, two-third and four-fifth of the statical tensile strength.
    The results are shown in Fig.6-(a), and we found that the dependence of stress amplitude on cycle number up to fracture exists, in other words the vitrified grinding wheels have fatigue behaviour.
  (4) For each stress amplitude, non-fracture probability is shown in Fig.7 (a), (b), (c), (d), where non-fracture probability is defined as the following.

    P = ( M - M f )/ M
    M : number of test pieces which are tested under given stress amplitude
    M f : number of test pieces which are tested under the given stress amplitude

Interruption of Explosions by Flame Arresters (3rd Report) --Quenching of Acetylen-Air Detonation--

RR-23-5
Toshihiro HAYASHI

: The fact that flames are unable to pass through narrow passages has been known as quenching phenomena. This principle is applicable for the direct quenching of detonation flames, using a quenching element with a large number of passages of small diameter. The assumption can be made that the quenching of detonation flame is composed of two processes ; the first is the decaying of detonation wave, which separates shock wave from a flame front, and the second process is a quenching of separated deflagration flame. Thus the quenching element should have an adequate thickness or passage diameter in order to perform above two roles. Commercial metal filters can be used as quenching elements of detonation arresters.
    This report describes about quenching abilities of sintered wire gauze and sintered metal against detonation flames propagating in stationary acetylene-air mixtures (initial pressure up to 2 kg/cm2 (g), acetylene content 4 - 15 %). Experiments are carried out in a, 1-inch enclosed tube, in which quenching element is inserted with a supporting perforated plate behind. Velocities of flame propagation are measured before and after the quenching element, and also an observation is made by an aid of thermocouple whether flame passed through the element or not.
    Main results are as follows ;
  1) It is found most difficult to quench flames of near-stoichiometric mixture of higher initial pressure. Detonation velocity is considered to have no substantial effect on flame transmission, because the maximum velocity is observed at 15 %, which is far from the stoichimetric value.
  2) Assuming that the quenching ability of wire gauze is evaluated by the Limiting Safe Pressure (L.S.P.), which is defined arbitrarily as a maximum pressure under which no flame pass through quenching element, L.S.P. can be related to the quantity of gauzes. But the relation between L.S.P. and flow resistance of gauze is not fully clarified.
  3) Even when gauzes failed to quench flames, detonation wave is always decayed. An average flame velocity (v) after gauzes shows a large decrease from the detonation velocity. The velocity v is found to decrease as the initial gas pressure decreases. At the limiting pressure of flame transmission, v seems to reach a constant value independent of acetylene content and the quantity of gauzes. This makes it possible to predict L.S.P. from the relation between v and initial pressures. For various conditions, predicted L.S.P. show good agreement with those determined experimentally.

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